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The early games feature Michael Vick, Ndamukong Suh and that weenie Jay Cutler. The night game features the Jets and the Cowboys. In between you'll see a bunch of teams who might move to Los Angeles.
I don't really know enough about the NFL to suggest a good drinking game, but if you really need help getting irresponsibly drunk, take down a beer every time an announcer explains how "the evidence must be indisputable" to overturn a call on replay. I never get tired of hearing that one, and they never get tired of saying it.
Enjoy the Week One action, you guys!